custom made tailor m的問題，透過圖書和論文來找解法和答案更準確安心。我們找到下列必買單品、推薦清單和精選懶人包

書中字有黃金屋讓自己更好的生活提案論文書籍站 custom made tailor m

custom made tailor m的問題，我們搜遍了碩博士論文和台灣出版的書籍，推薦Taschen寫的 The adidas Archive. The Footwear Collection 和Cantwell, Marianne的 Be a Free Range Human: Escape the 9-5, Create a Life You Love and Still Pay the Bills都可以從中找到所需的評價。

這兩本書分別來自和所出版。

國立臺灣科技大學應用科技研究所鄭智嘉所指導 Ashenafi Zeleke Melaku的自組裝超分子聚合物輔助二維奈米材料的可擴展液相剝離和分散（2021），提出custom made tailor m關鍵因素是什麼，來自於。

而第二篇論文國立交通大學應用化學系碩博士班吳淑褓所指導 N. THIRUMALAIVASAN的設計與合成多功能化學感測分子與孔洞二氧化矽奈米載體用硫化氫啟動腫瘤靶向藥物的釋放（2019），提出因為有化學感測分子、孔洞二氧化矽奈米載體、carbon dots的重點而找出了 custom made tailor m的解答。

custom made tailor m

The adidas Archive. The Footwear Collection
為了解決custom made tailor m的問題，作者Cantwell, Marianne 這樣論述
為了解決custom made tailor m的問題，作者N. THIRUMALAIVASAN 這樣論述

The adidas Archive. The Footwear Collection

為了解決custom made tailor m的問題，作者Taschen 這樣論述：

　　運動鞋迷心中的麥加:足球金童梅西、流行指標瑪丹娜都愛穿！　　首次愛迪達的視覺回顧集，首度公開不曾看過的樣鞋! 　　這本收藏集是首次愛迪達的視覺回顧，收錄357款型號，包含不曾看過的樣鞋與獨一無二的經典款。　　書中的照片來自「愛迪達歷史資料庫」(adidas Historical Archive)，是全球數一數二最大運動商品製造商的檔案，由知名攝影師Christian Habermeier與Sebastian Jäger用影像詳細記錄至今。　　攝影使用高規格的重現技術，影像呈現最細膩的細節，還有每一個穿鞋者背後的故事—網羅明星客製款:從瑪丹娜到球星梅西;聯名設計款:從美國饒舌歌手

Kanye West、時裝設計師Stella McCartney與山本耀司到環保組織Parley for the Oceans，皆收錄在書中。　　從這本收藏集裡，不只看到設計，還有愛迪達從1919至今我們的運動、設計與文化歷史的第一手見證。　　It all started in their mother’s laundry room in the quiet German town of Herzogenaurach. There, Adolf Dassler—known to everyone as “Adi”—and his brother Rudolf made their fi

rst pair of sports shoes. Hundreds of groundbreaking designs, epic moments, and star-studded collabs later, this book presents the first visual review of the adidas shoe through more than 357 models including never-before-seen prototypes and one-of-a-kind originals. 　　To further develop and tailor

his products to athletes’ specific needs, Dassler asked them to return their worn footwear when no longer needed, with all the shoes eventually ending up in his attic (to this day, many athletes return their shoes to adidas, often as a thank you after winning a title or breaking a world record). Thi

s collection now makes up the adidas Historical Archive, one of the largest, if not the largest archive of any sports goods manufacturer in the world—which photographers Christian Habermeier and Sebastian Jäger have been visually documenting in extreme detail for years. 　　Shot using the highest rep

roduction techniques, these images reveal the fine details as much as the stains, the tears, the repair tape, the grass smudges, the faded autographs. It’s all here, unmanipulated and captured in extremely high resolution—and with it comes to light the personal stories of each individual wearer. We

encounter the shoes worn by West Germany’s football team during its “miraculous” 1954 World Cup win and those worn by Kathrine Switzer when she ran the Boston Marathon in 1967, before women were officially allowed to compete; custom models for stars from Madonna to Lionel Messi; collabs with the lik

es of Kanye West, Pharrell Williams, Raf Simons, Stella McCartney, Parley for the Oceans or Yohji Yamamoto; as well as the brand’s trailblazing techniques and materials, like its pioneering use of plastic waste that is intercepted from beaches and coastal communities. 　　Accompanied by a foreword by

designer Jacques Chassaing and expert texts, each picture tells us the why and the how, but also conveys the driving force behind adidas. What we discover goes beyond mere design; in the end, these are just shoes, worn out by their users who have loved them—but they are also first-hand witnesses of

our sports, design, and culture history, from adidas’s beginnings in 1919 until today. Concept and photography by Christian Habermeier has been working as a photographer and designer since 1989. He studied taught communication design and has taught photography and digital illustration from 2000 to

2006. His own projects span from Cuba, Kenya, Nepal, India, Switzerland, to Hong Kong. 　　Sebastian Jäger studied design at the Georg-Simon-Ohm University of Applied Sciences in Nuremberg, focusing on moving images and photography, where he met former lecturer Christian Habermeier in 2005. Their joi

nt company studio waldeck photographers serves customers from industry and the cultural sector. Since 2011, they have been creating a visual record of the holdings of the historical adidas archive.

自組裝超分子聚合物輔助二維奈米材料的可擴展液相剝離和分散

為了解決custom made tailor m的問題，作者Ashenafi Zeleke Melaku 這樣論述：

近期，二維 (2D) 奈米材料在許多應用領域中展現出十足的潛力，如石墨烯、過渡金屬二硫屬化物 (TMDCs)、六方氮化硼 (h-BN) 等，已應用於各種光電元件、傳感器、電容器、太陽能電池等方面。此等材料雖只有單顆或數顆原子之厚，卻擁有在塊材型態不具備的優越特性，使其在未來廣泛的科技研究中展現出色前景。然而，材料性能固然出色，工業級大量生產高質量的二維奈米材料卻非易事，而液相脫層程序正是合適的因應之道，透過界面活性劑與溶劑的搭配，可以簡單、環保的方式有效地大規模產生薄層二維材料。在本文研究中，我們分別在石墨與二硫化鉬(MoS2)兩系統中加入超分子聚合物作為界面活性劑，經由超音波震盪的處理，將

兩材料由三維(3D)大型分子轉為二維形式並大量生產。在研究的第一部分，利用添加腺嘌呤功能化的生物可降解低聚物(3A-PCL)，將塊狀結晶的石墨脫層為具導電性、良好物理特性且高度有序結構的石墨烯奈米片，經檢驗後可證明，因3A-PCL對石墨表面具有高親和性，可於其表面自行組裝為層狀奈米結構，在有機溶劑裡脫層並形成穩定懸浮的石墨烯奈米片。而在移除溶劑後，此複合材料在黏性與彈性狀態間顯示出持久的熱可逆相變行為，並可透過調整複合材料內的聚合物比例，進而調控脫層石墨烯的厚度。此石墨烯複合材料最大的特色在於電阻率低，測得之數值為1.5 ± 0.7 mΩ·cm，比原始石墨烯低一個數量級以上。綜合第一實驗系統的

研究，選用液相脫層程序製備多功能超分子與石墨的奈米複合材料，因其生產過程簡單，製成之材料具有良好的物理特性與導電性，適合在導電元件領域發展應用。本研究的第二部分，我們以鄰二氯苯(ODCB)為溶劑，腺嘌呤功能化聚丙二醇(A-PPG)為界面活性劑，設計一種能將石墨脫層為厚度可控之高質量石墨烯的實驗系統。首先我們先在溶劑ODCB中，把天然石墨剝離為數層有序的脫層石墨(EG)奈米片，此視為一次脫層；而在二次脫層中，在EG溶液中加入A-PPG，此時具氫鍵官能基的腺嘌呤發揮關鍵作用，使A-PPG能在石墨烯奈米片表面自行組裝為長而有序的奈米結構，進而增加EG在ODCB中的長期分散穩定性，且透過調整複合材料中

A-PPG的含量，可製備出具特定結構特徵的石墨烯奈米片。此以超分子聚合物作非共價官能化的石墨烯表現非凡，經由簡單、有效的一次及二次脫層，可自由調控石墨烯的所需厚度，在各項潛在應用中發揮作用。最後一實驗系統，則是以水為溶劑，胞嘧啶功能化聚丙二醇(Cy-PPG)為界面活性劑，搭配二次脫層程序，將MoS2剝離為超薄層的奈米片。首先，利用水相環境將原始的MoS2初步分散為數層的奈米片，接著於二次脫層期間加入Cy-PPG，與數層MoS2的水溶液進行一小時以上的超音波震盪，此過程中，自組裝為有序層狀奈米結構的Cy-PPG會因強物理作用力而吸附在奈米片的表面，並形成可調節的超薄層MoS2，而透過仔細調整Cy

-PPG的用量，可以大幅改善MoS2在水溶液的長期穩定分散性，從而保持其固有的特性，最後利用光譜及顯微鏡分析脫層奈米片的形貌與物理性質，證明MoS2奈米片表面確實有Cy-PPG的存在，而在導電率測試中，測得之數值則較原始MoS2高出127 µS/cm。綜觀以上，此實驗系統能夠有效以環保方法生產超薄層MoS2奈米片，對於講求材料精準的研究領域至關重要。

Be a Free Range Human: Escape the 9-5, Create a Life You Love and Still Pay the Bills

為了解決custom made tailor m的問題，作者Cantwell, Marianne 這樣論述：

Trapped in a job or business that's "just not you"? Always dreaming of your next vacation or living for the weekend? Marianne Cantwell's straight-talking bestseller will help you break out of that career cage and Be A Free Range Human. It's about much more than just quitting your job and becoming yo

ur own boss. It's about life on your terms, working when, where and how you want - so you don't have to fit yourself into someone else's box to make a great income. This second edition won't just inspire you, it will give you unconventional and practical steps to: - Discover what you really want to

do with your life (even if no answer has ever fully fit)- Get started in 90 days, with what you have- Create a free range career, tailor-made for you and the life you want (be it travelling the world or hanging out in your favourite caf )- Stand out from the crowd and get paid well to be you Be A Fr

ee Range Human was one of the first and most popular guides to creating a custom career (without an office or a boss). Updated with new advice on how to make free range work for your personality (you don't need to be a constantly-networking extrovert. have an MBA, or get funding), this smart, energi

zing guide will help you cut through the noise, see your options in a new way, and get the freedom and fulfilment you crave. Marianne Cantwell is an expert on creating a free range career and a successful work-life that fits who you really are (and the life you want). The founder of Free Range Hum

ans, and a leading TEDx speaker, thousands have done her courses on finding your ’thing’ (and making it work for you). Her thinking has featured everywhere from Business Week and CBS MoneyWatch, to The Guardian, Daily Mail and Entrepreneur magazine. A corporate escapee herself, she now lives and wor

ks in several countries (often between London and sunny California), and carries her business in a little laptop.

設計與合成多功能化學感測分子與孔洞二氧化矽奈米載體用硫化氫啟動腫瘤靶向藥物的釋放

為了解決custom made tailor m的問題，作者N. THIRUMALAIVASAN 這樣論述：

Table of contentsS. No. Contents Page No.Abstract iAcknowledgements vAbbreviations viTable of contents viiiList of Figures xList of Schemes xviiSupplementary Information xviiiChapter I 11 Introduction 11. 1 Strategy for designing fluorescent chemosensors. 1

1. 1. 1 Why we need to design chemosensors for hydrogen sulfide (H2S)? 21. 1. 2 Literature survey 41. 2 Smart nanocarrier for targeted drug delivery 51. 2. 1 Size and shape tenability of MSNP 61. 2. 2 Importance of hydrogen sulfide-responsive mesoporous silica nanocarrier

for targeted drug delivery 71. 2. 3 Literature review 91. 3 Design and synthesis of fluorescent carbon dots 111.3. 1 Multifunctional selective sensing fluorescent carbon dot 111. 3. 2 Literature review 121. 3. 3 Research purpose 13Chapter II Highly selective turn-

on probe for H2S with imaging applications in vitro and in vivo 142. 1 Experimental 152. 1. 1 Materials and instrumentation 152. 1. 2 Synthesis of PyN3 152. 1. 3 The reduction product 1-aminopyrene from the reaction of PyN3 with H2S 162. 1. 4 Cytotoxicity assay 162.

1. 5 Cell culture and confocal fluorescence imaging of PyN3 in living cells 162. 1. 6 H2S imaging in zebrafish 172. 2 Results and discussion 17Conclusions 27Chapter III An In Vitro and In Vivo Approach of Hydrogen Sulfide-Responsive Drug Release Driven by Azide-Functionalize

d Mesoporous Silica Nanoparticles 283.1 Experimental section 293. 1. 1 Materials and chemicals 293. 1. 2 Instruments 293. 1. 3 Synthesis of (2-azido-1,3-phenylene)dimethanol 303. 1. 4 Synthesis of MSNP-NH2 303. 1. 5 Synthesis of MSNP-N3 313. 1. 6 Synthesis o

f DOX-loaded MSNP-N3-FA 313. 1. 7 Drug release profile 313. 1. 8 MTT cytotoxicity assay 313. 1. 9 Live cell imaging 323. 1. 10 In vivo antitumor efficacy 323. 1. 11 H&E and TUNEL staining 323. 2 Results and discussion 33Conclusion 53Chapter IV Lysosome targe

table bright luminescent carbon dots for multifunctional selective sensing and imaging application in living cells 544. 1 Experimental section 554. 1. 1 Materials and instrumentation 554. 1. 2 Preparation of CDs 554. 1. 3 Determination of quantum yield (Qy) 564. 1. 4 Bi

otoxicity of Luminescence CDs 564. 1. 5 Cell culture and imaging 564. 2 Results and discussion 57Conclusion 72Reference 78List of FiguresS. No. Contents Page No.Fig. 1. 1 Graphical illustration of chemosensor. 2Fig. 1. 2 Endogenous H2S formation through an enzymat

ic pathway. 3Fig. 2. 1 Schematic diagram of probe PyN3 for H2S and imaging applications in living cells and zebrafish. 14Fig. 2. 2 Fluorescence changes of PyN3 (10 µM) upon the addition of various anions in H2O–DMSO (v/v = 20/80) solutions. The excitation wavelength was 410 nm. 18Fig

. 2. 3 Time-dependent ﬂuorescence intensity changes of PyN3 (10μM) upon addition of H2S (15eqiv). The spectra were recorded in pH 7.4 H2O–DMSO (v/v = 20/80) at 25 °C under excitation wavelength was 410 nm 19Fig. 2. 4 Fluorescence changes of PyN3 (10 µM) with gradual addition of H2S in H2O–D

MSO (v/v = 20/80) the excitation wavelength was 410 nm. 19Fig. 2. 5 Normalized response of fluorescence signal to changing H2Sconcentrations. 20Fig. 2. 6 HPLC analysis of (a) compound PyN3, (b) PyN3+Na2S and (c) the reaction product of PyN3+Na2S. 21Fig. 2. 7 Fluorescence intensity

at 455 nm of the probe PyN3 (10 µM) with various species (15 eqiv) in a H2O–DMSO solution (v/v = 20/80). The black bars represent single species (150 μM); the gray bars represent coexisting species: H2S (150 μM) + other species (150 μM). The excitation wavelength was 410 nm. 22Fig. 2. 8 The ef

fect of pH on the ﬂuorescence changes of PyN3 (10 µM) and after the addition of H2S (150 µM) in a H2O–DMSO (v/v = 20/80) solution. The excitation wavelength was 410 nm. 22Fig. 2. 9 MTT assay of MCF-7 cells in the presence of PyN3 (0–25 µM) at 37◦C for 24 h. 23Fig. 2. 10 Confocal ﬂuoresce

nce images of MCF-7. (Left) Fluorecence; (Middle) PI (propidium iodide, nuclearstain); and (Right) merged image. (A)The cells were incubated with PyN3 (10 µM) alone for 15 min. (B)Cells were treated with H2S (150 μM) for 30 min. (C) Cells were treated with SNP (50 μM) for 30 min. 24Fig. 2. 11

Confocal ﬂuorescence images of HeLa. (Left) Fluorecence; (Middle) PI (propidium iodide, nuclear stain); and (Right) merged image. (A)The cells were incubated with PyN3 (10 µM) alone for 15 min. (B) Cells were treated with H2S (150 μM) for 30 min. (C) Cells were treated with SNP (50 μM) for 30 min.

25Fig. 2. 12 Confocal fluorescence images of HCT-116 and HT-29 cells. (left) Bright field; (middle) fluorescence; and (right) merged image. The HCT-116 and HT-29 cells were incubated with PyN3 (10 μM) alone for 1.3 h. 26Fig 2. 13 Confocal microscopy images of 3-day-old zebrafish. (A) The

zebrafish incubated with PyN3 (10 μM) for 30 min. (B) Subsequent treatment with H2S (150 μM) for 2 h. 26Fig. 3. 1 Surface functionalization on MSNPs. (A) Stage I: anchor a stalk containing an azide group; stage II: Dox loading and cape with a rotaxane on the surface of MSNP-N3; stage III: atta

ch a folic acid as a stopper; stage IV: drug release triggered by H2S. (B) Mobilization of DOX-loaded MSNP-N3-FA into HT-29 cells and H2S triggered drug release inside the cell. 28Fig. 3. 2 (a) Particle size analysis of MSNP-N3 by DLS. (b) SEM image of MSNP-N3. 35Fig 3. 3Fig. 3. 4 HR-TEM

images of MSNP-N3. Image scale bar of (a-b) 50 and 20 nm respectively. The inset shows the interplanar distance of d100 planes and the thickness of the mesopore wall.AFM images of (a) MSNP-NH2 and (b) MSNP-N3-FA. Particles thickness analysis of (c) MSNP-NH2 and (d) MSNP-N3-FA. (e) HR-TEM images of

MSPN-N3-FA. 3536Fig. 3. 5 The X-Ray diffraction pattern of MSPN-N3 with a calculation of interplanar spacing in mesoporous structure. 37Fig. 3. 6 (A) N2 adsorption-desorption isotherms and (B) pore distributions of MSNP-NH2, MSNP- N3. 38Fig. 3. 7 FT-IR spectra of (a) MSNP-OH, (b) M

SNP-NH2, (c) MSNP-N3 (d) MSNP-N3-CD and (e) MSNP-N3-FA. 38Fig. 3. 8 13C CP/MAS NMR spectrum of MSNP-N3. 39Fig. 3. 9 Zeta potential values of different mesoporous silica nanoparticles during the functionalization (a) MSNP-OH, (b) MSNP-NH2, (c) MSNP-N3 (d) MSNP-N3-FA. 40Fig. 3. 10 Th

ermogravimetric analysis of (a) MSNPs (b) MSNP-NH2, (c) MSNP-N3, (d) MSNP-N3-FA and (e) Fluorescein loaded MSNP-N3-FA. 41Fig. 3. 11 Absorption spectra of fluorescein (FL) before loading ( ) and after loading (-----) under different nanoparticle-to-fluorescein loading weight ratios. Weight ra

tio of FLmg/MSNPmg is from 0.5:10 to 4:10. 42Fig. 3. 12 Fluorescein loading capacity of MSNP-N3 using diﬀerent weight ratios (nanoparticle to fluorescein). 42Fig. 3. 13 (a-e) Fluorescein release from MSNP-N3-FA in the presence of different H2S concentrations (0, 0.1 mM, 1, mM, 3 mM, 5 mM

, respectively). 43Fig. 3. 14 The evaluation of cell viabilities of (A) HT-29 cells and (B) HeLa cells treated with nanoparticles and free Dox for 24 h. The amount of free Dox is the same as the amount of Dox loaded in MSNPs. 44Fig. 3. 15 Flow cytometry histogram of HT-29 cell line. (A)

The plot of (a) control HT-29 cell, (b) with MSNP-N3-FA for 8h incubation, (c) with fluorescein for 8h incubation, (d) and (e) fluorescein loaded MSNP-N3-FA for 6h and 8 h incubation, respectively. (B) Overlay plot of (a) control, (b) MSNP-N3-FA for 8h (c) fluorescein for 8h, (d) and (e) fluorescein

loaded MSNP-N3-FA for 6h and 8 h, respectively. 46Fig. 3. 16 Fluorescence cell imaging of (a-c) HeLa cells, (d-f) HCT-116 cells, (g-i) HT-29 cells, (j-l) A2780 cells and (m-o) SKOV-3 cells treated with 50 μg mL−1 Dox-loaded MSNP-N3-FA for 6 h. (Left) Bright field; (Middle) DOX; and (Right) me

rged image. 47Fig. 3. 17 Fluorescence images of HT-29 and HCT-116 cells treated with 50 μg mL−1 of Dox-loaded MSNP-N3-FA for 6 h. (a, e) Bright field, (b, f) nuclear staining dye (DAPI), (c, g) Dox channel, (d, h) merged image of (a-c) and (e-g), respectively. Scale bar 25 µm. 48Fig. 3. 18

Fluorescence microscopic images of HT-29 cells after being treated with 50μg mL−1 of Dox-loaded MSNP-N3-FA for 10, 12 and 15hrs. (a, e, i) Bright field, (b, f, j) Nuclear staining dye (DAPI) (c, g, k) Dox channel, (d, h, l) merged image of a, b and c. 48Fig. 3. 19 Flow cytometric analysis o

f apoptosis by AnnexinV-FITC/PI double-staining assay. Induction of apoptosis by (a) control, (b) MNSP-N3-FA, (c) free DOX, and (d) DOX-MNSP-N3-FA in HT-29 cells. 49Fig. 3. 20 Antitumor efficacy of DOX-loaded MANP-N3-FA in vivo. (n=5) *p < 0.05 A) Changes in tumor growth curves after intra-art

erial injection of PBS, Free DOX, MSNP-N3-FA, and DOX-loaded MANP-N3-FA in HT-29 tumor-bearing nude mice. B) Comparison of the tumor weight changes. (C) The relative body weight changes after different treatments. 50Fig. 3. 21 Photograph of the collected HT-29 tumor bearing tissues with each t

reatment after 30 days. 51Fig. 3. 22 (A) Histological analysis of tumor tissues treated with different MSNPs. Tumor tissues were stained with hematoxylin (blue) and eosin (pink). (B) TUNEL detection of apoptotic cells in tumor tissues with different treatments. The tumor tissues were stained w

ith fluorescein (green) and Hoechst 33258 (red). Scale bar = 30 µm. 52Fig. 4. 1 Characterization properties of carbon dots (a) High resolution-TEM images of CDs, scale bar= 100 nm. (b) AFM image of CDs. (c) Dynamic light scattering (DLS) measurement of CDs. (d) FT-IR spectra of CDs. (e) Raman

spectra of CDs. (f) XPS spectra of CDs. 58Fig. 4. 2 Optical properties of the carbon dots (a) Uv-vis absorption (black line) and fluorescent emission (green line) spectra of CDs. (b) Excitation dependence fluorescent emission spectra of the CDs under different ranging from 320 nm to 500 nm. (c

) The color coordinate of the CDs (0.389, 0.493). 59Fig. 4. 3 CDs (0.1mg mL-1) fluorescent emission intensity changes in the presence of various concentration of (a) triphosgene (0-150 µM) in chloroform solvent. (b) upon addition of various nerves mimic agents with the same concentrations of 1

50 µM in chloroform solvent. (C) Photograph of test paper on CDs fluorescence response upon exposure with different (0-50 ppm) level of triphosgene vapor for 30 min at room temperature. λ ex =410 nm. 61Fig. 4. 4 UV- vis spectral change of CDs upon addition of (a) nerve mimic agents (150 μM) in

chloroform solution. (b) 0- 150 μM of triphosgene. (c) Linear calibration plot of CDs in the presence of triphosgene(30-90 μM) at λ ex =410 nm. 62Fig. 4. 5 (a) CDs (0.05mg mL-1) fluorescence spectra of interaction with various metal ions at a concentration of 100 µM in aqueous solution. (b)

Fluorescent intensities of CDs-Ag+ complex with different amino acids (100 µM) in aqueous solution. λ ex =410 nm. 63Fig. 4. 6 (a) UV-vis spectram of CDs (0.05mg mL-1) in the presence of various metal ions (100 μM) in DI.H2O. (b) CD-Ag+ complex with 100 μM of different amino acids. 64Fig. 4.

7 (a) Fluorescence spectra of CDs upon addition of various concentration of (0-100 µM) of Ag+ ion in aqueous solution. (b) CDs-Ag+ complex solution was titrating with (0-100 µM) of Cys in aqueous solution. inset in a and b: changes of emission intensity with increasing the concentration of analy

te concentrations. λ ex =410 nm. 64Fig. 4. 8 UV- vis absorbance changes of CDs upon addition of (a) (1-100 μM) of Ag+ ions. (b) CD- Ag+ complex with various concentrations of cystine (1-100 μM). 65Fig. 4. 9 Linear calibration plot of CDs with (a) Ag+ ions and (b) CD-Ag+ complex with va

rious concentrations of Cys. λ ex =410 nm. 65Fig. 4. 10 Reaction time profile of CDs with a) triphosgene (0- 150 μM). b) Ag+ ions (1-100 μM). and c) CD- Ag+ complex with various concentrations of cystine (1-100 μM). λ ex =410 nm. 66Fig. 4. 11 Cellular toxicity of CDs on HCT-116, SKOV3 an

d HeLa cells.68Fig. 4. 12 Confocal fluorescence images of HeLa cells incubated with CDs. The fluorescent images were collected at different excitation wavelengths of (g) 350 nm, (h) 480 nm, and (i) 550 nm. Scale bar: 10 μm. 69Fig. 4. 13 (a) Confocal fluorescence images of HCT-116 living cel

ls incubated with CDs (0.1mg mL-1) for 30 min. (b) Further cells were incubated with 200 µM of Ag+ ions for 20 min. (c) Finally, CDs and Ag+ incubated cell line was treated with 100 µM of Cys for 20 min. Scale bar = 10µm. 69Fig. 4. 14 Confocal fluorescence cell images for monitoring of Lysosom

e targeting CDs after 1 h incubation. (a-c) cell images of ovarian cancer SKOV3 cell line. (f-h) cell image of cervical cancer HeLa cells incubated with CDs Lyso tracker deep red. the images were collected from 500-550 nm. (d, i) Lyso tracker deep red and CDs correlation pot of SKOV3 and Hela cells

intensities. (e, f) The intensity profile for the region of interest (ROI) cross of SKOV3 and Hela cells, respectively. Scale bar = 10µm. CDs concentration is 0.1mg mL-1. 70Fig. 4. 15 Photograph of fluorescent CDs (a) fingerprint image on aluminum foil. (b) Fluorescent character on filter pape

r under UV light. 71Fig. 4. 16 Confocal fluorescence image of CDs (0.1mg mL-1) stained fingerprint on glass slide. (a) DIC, (b) λex=350 nm (c) λex=480 nm (d) λex=550 nm (e) overlay image. Scale bar: 500µm. 71List of SchemesS. No. Contents Page No.Scheme 1. 1 Chemical structure of t

he fluorescent probe CyT for hydrogen sulfide (H2S) selective sensing and its recovery induced by the acidic condition. 4Scheme 1. 2 The chemical structure of fluorescence probe 1, its reaction with H2S. 5Scheme 1. 3 Colorimetric and ratiometric sensing of H2S by NS1. 5Scheme 1. 4

Schematic of synthesis of MCM-41 with CTAB surfactant micelles as a template. 7Scheme 1. 5 Schematic representation of the preparation and cancer cell internalization of the Tf‐capped HMSNs nanocarriers with both tumor-targeting and GSH stimuli-responsive properties. 9Scheme 1. 6 Schemat

ic representation of pH-triggered release of drug molecules from GQD-capped MSNPs. 10Scheme 1. 7 (a) The synthetic route for the preparation of MSNP–SS–ssDNA, and (b) illustrative mechanism of dual-responsive drug release from oligonucleotide capped MSNPs. 11Scheme 1. 8 DAN-GQD preparat

ion and detection of phosgene. 12Scheme 1. 9 Bright yellow Y-CDs preparation, cellular imaging and three states of bifunctional sensing. 13Scheme 2. 1 Synthesis of PyN3. 17Scheme 2. 2 Proposed detection mechanism of PyN3. 20Scheme 3. 1 Synthesis of H2S responsive MSNPs; doxor

ubicin/fluorescein are loaded in the nanoparticles and are released upon H2S triggered removal of Folic acid stopper. 34Scheme 4. 1 Schematic illustration for solvothermal based bright luminescent CDs preparation strategy. The CDs can selective fluorescent sensing of multi-analyte platform for

Ag+, Cys and triphosgene and its potent lysosomal targeting ability. 54Supplementary InformationS. No. Contents Page No.Fig. 2S-1 1H-NMR spectra of compound 1-Aminopyrene in DMSO-d6. 73Fig. 2S-2 13C-NMR spectra of compound 1-Aminopyrene in DMSO. 73Fig. 2S-3 ESI-MS spectrum o

f 1-Aminopyrene with Na2S. 74Fig. 2S-4 1H-NMR spectra of compound PyN3 in DMSO-d6.74Fig. 2S-5 13C-NMR spectra of compound PyN3 in DMSO-d6. 75Fig. 2S-6 EI-MS spectrum of PyN3. 75Fig. 3S-1 1H NMR spectrum of compound (2-azido-1, 3-phenylene) dimethanol. 76Fig. 3S-2 13C NMR s

pectrum of compound (2-azido-1, 3-phenylene) dimethanol. 76Fig. 3S-3 EI-MS spectrum of (2-azido-1, 3-phenylene) dimethanol. 77

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設計與合成多功能化學感測分子與孔洞二氧化矽奈米載體用硫化氫啟動腫瘤靶向藥物的釋放

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